ChemSphere
67Ho164.93

Holmium

Lanthanide · Period 6 · f-block

The most magnetic atom nature makes

Atomic mass
164.93 u
State at 25 °C
Solid
Electronegativity
1.23
Melting point
1,460.9 °C
Boiling point
2,599.9 °C
Configuration
[Xe] 4f11 6s2
Building atom…
67 protons 98 neutrons 67 electrons

Nucleus drawn at reduced count for clarity. Drag to rotate.

Holmium, explained

Video lesson in production

Bhavya’s explainer for this element will play here.

Overview

Holmium is a soft, silvery lanthanide with the configuration [Xe]4f11 6s2. It forms the Ho3+ ion, whose ten 4f electrons arrange themselves to give the highest magnetic moment of any naturally occurring element, about 10.6 Bohr magnetons. Because of this, holmium is used for the pole pieces that concentrate the field in the strongest static laboratory magnets. The metal itself becomes ferromagnetic only below about 20 K.

Holmium's sharp 4f absorption bands give its compounds unusual colours. Holmium oxide looks pale yellow in daylight but pinkish under fluorescent lighting, because its narrow absorption lines interact differently with the two kinds of light. Those same sharp bands make holmium oxide solutions and glass a standard for calibrating spectrophotometer wavelengths. In medicine, holmium-doped YAG lasers emit at 2.1 micrometres, a wavelength strongly absorbed by water, so they can shatter kidney stones and cut tissue with little damage to surrounding areas.

Discovery

In 1878 Swiss chemists Marc Delafontaine and Jacques-Louis Soret noticed unknown absorption lines in erbium samples and called the source 'element X'. Working independently in 1878–79, Swedish chemist Per Teodor Cleve separated the oxide from erbia and named it holmia, from Holmia, the Latin name of his home city, Stockholm. Pure holmium oxide was later prepared, and the metal was first isolated in reasonably pure form in the 20th century.

Where it’s found
About 1.3 parts per million of Earth's crust, extracted from monazite, gadolinite and ion-adsorption clays.
What it’s used for
  • Ho:YAG surgical lasers
  • Magnet pole pieces
  • Spectrophotometer calibration
  • Yellow and red glass colouring
  • Reactor neutron absorbers
In living things
No biological role; holmium salts have low toxicity.
Safety
Bulk metal is relatively safe; powders are flammable and should be kept from ignition sources.

How it compares

Where Holmium sits among all 118 elements on the trends that shape the table.

  • Electronegativity1.23Pauling

    #76 of 100 elements with data

  • Ionization energy581kJ/mol

    #76 of 104 elements with data

  • Atomic radius175pm

    #25 of 95 elements with data

  • Electron affinity32.6kJ/mol

    #69 of 109 elements with data

  • Density8.79g/cm³

    #50 of 114 elements with data

  • Melting point1,730K

    #32 of 110 elements with data

Density
8.79 g/cm³
Atomic radius
175 pm
Covalent radius
166 pm
Molar heat
27.15 J/(mol·K)
Appearance
silvery white
Discovered by
Marc Delafontaine

Inside the atom

67 electrons arranged in 6 shells: 2 · 8 · 18 · 29 · 8 · 2.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f11 · shorthand [Xe] 4f11 6s2

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d10
  8. 4p6
  9. 5s2
  10. 4d10
  11. 5p6
  12. 6s2
  13. 4f11

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Holmium bonds.

Ionization energies

Energy to remove each electron in turn, on a log scale. Each electron is harder to remove than the last, because the remaining ones feel more of the nucleus.

Signature reactions

The chemistry Holmium is known for.

  1. Redox · Combustion

    Burning in air

    Holmium burns readily to form holmium(III) oxide, a pale yellow powder whose colour shifts under different lighting. Its sharp absorption bands make it useful for calibrating optical instruments.

    4Ho(s)+3O2(g)2Ho2O3(s)

    Conditions: heating in air

  2. Redox · Single displacement

    Dissolving in sulfuric acid

    Holmium dissolves with fizzing to form yellow Ho3+ ions in solution. The solution shows the sharp absorption lines that first revealed the element.

    2Ho(s)+3H2SO4(aq)2Ho3+(aq)+3SO42−(aq)+3H2(g)

    Conditions: dilute acid, room temperature

  3. Acid–base

    Oxide with nitric acid

    The basic oxide neutralises nitric acid to give holmium nitrate. Nitrate solutions like this are fed into solvent-extraction plants that separate holmium from its neighbours.

    Ho2O3(s)+6HNO3(aq)2Ho(NO3)3(aq)+3H2O(l)

    Conditions: warm dilute acid

Where you’ll meet it

Research

No research on Holmium yet

When Bhavya publishes a project that studies Holmium, it will be linked here.

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