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66Dy162.5

Dysprosium

Lanthanide · Period 6 · f-block

The 'hard to get' metal that keeps electric-car magnets strong

Atomic mass
162.5 u
State at 25 °C
Solid
Electronegativity
1.22
Melting point
1,406.9 °C
Boiling point
2,566.9 °C
Configuration
[Xe] 4f10 6s2
Building atom…
66 protons 97 neutrons 66 electrons

Nucleus drawn at reduced count for clarity. Drag to rotate.

Dysprosium, explained

Video lesson in production

Bhavya’s explainer for this element will play here.

Overview

Dysprosium is a bright, silvery lanthanide with the configuration [Xe]4f10 6s2. Like its neighbours it forms the Dy3+ ion almost exclusively, and the close similarity in size and charge among the heavy lanthanides is what made it so hard to separate. Its partly filled 4f shell carries a large magnetic moment, and the metal orders magnetically when cold: it is ferromagnetic below about 85 K and has a helical magnetic structure between 85 and 179 K.

Dysprosium's main job today is in neodymium-iron-boron magnets. Adding a few percent of dysprosium raises the magnets' coercivity, their resistance to being demagnetised, especially at the 100–200 °C reached inside electric-vehicle motors and wind-turbine generators. Because supply is concentrated in a few deposits, dysprosium is regularly listed as a critical raw material. Its isotopes also absorb neutrons well, so dysprosium oxide and titanate are used in reactor control rods, and its iodide gives metal-halide lamps an intense white light.

Discovery

French chemist Paul-Émile Lecoq de Boisbaudran identified dysprosium in 1886 in a sample of holmium oxide. He separated it by repeatedly dissolving the oxide in acid and precipitating it with ammonia, needing more than 30 attempts before he succeeded. He named it from the Greek dysprositos, 'hard to get at'. A reasonably pure metal was not obtained until the 1950s, when Frank Spedding's group at Iowa State University developed ion-exchange separation.

Where it’s found
About 5 parts per million of Earth's crust; most comes from ion-adsorption clays in southern China and Myanmar, with some from xenotime and monazite.
What it’s used for
  • High-temperature NdFeB magnets
  • Electric-vehicle motors
  • Wind-turbine generators
  • Reactor control rods
  • Metal-halide lamps
  • Terfenol-D actuators
In living things
No known biological role; soluble dysprosium salts are mildly toxic if swallowed.
Safety
Low hazard as bulk metal, but fine dust can ignite, and burning rare-earth metals should not be doused with water.

How it compares

Where Dysprosium sits among all 118 elements on the trends that shape the table.

  • Electronegativity1.22Pauling

    #77 of 100 elements with data

  • Ionization energy573kJ/mol

    #82 of 104 elements with data

  • Atomic radius175pm

    #25 of 95 elements with data

  • Electron affinity34kJ/mol

    #65 of 109 elements with data

  • Density8.54g/cm³

    #53 of 114 elements with data

  • Melting point1,680K

    #35 of 110 elements with data

Density
8.54 g/cm³
Atomic radius
175 pm
Covalent radius
167 pm
Molar heat
27.7 J/(mol·K)
Appearance
silvery white
Discovered by
Lecoq de Boisbaudran

Inside the atom

66 electrons arranged in 6 shells: 2 · 8 · 18 · 28 · 8 · 2.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f10 · shorthand [Xe] 4f10 6s2

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d10
  8. 4p6
  9. 5s2
  10. 4d10
  11. 5p6
  12. 6s2
  13. 4f10

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Dysprosium bonds.

Ionization energies

Energy to remove each electron in turn, on a log scale. Each electron is harder to remove than the last, because the remaining ones feel more of the nucleus.

Signature reactions

The chemistry Dysprosium is known for.

  1. Redox · Single displacement

    Dissolving in acid

    Dysprosium dissolves readily in dilute acids, releasing hydrogen and forming pale yellow-green Dy3+ ions. This is the first step in many separation and recycling processes.

    2Dy(s)+6H+(aq)2Dy3+(aq)+3H2(g)

    Conditions: dilute acid, room temperature

  2. Redox · Combustion

    Burning in air

    Dysprosium burns to form dysprosium(III) oxide, a white powder that is strongly attracted to a magnet. This oxide is the common commercial form of the element.

    4Dy(s)+3O2(g)2Dy2O3(s)

    Conditions: heating in air

  3. Redox · Synthesis

    Forming dysprosium iodide

    Dysprosium combines directly with iodine to give greenish DyI3. Inside metal-halide lamps this salt vaporises in the hot arc and emits a dense set of spectral lines that adds up to bright white light.

    2Dy(s)+3I2(g)2DyI3(s)

    Conditions: heating in iodine vapour

Where you’ll meet it

  • Neodymium magnet

    Neodymium magnet

    Dysprosium is added to many NdFeB magnets so they hold their strength when hot.

    Photo: Wikimedia Commons
  • Wind turbine

    Wind turbine

    Direct-drive wind turbines use tonnes of rare-earth magnets that often contain dysprosium.

    Photo: Wikimedia Commons
  • Toyota Prius

    Toyota Prius

    Hybrid and electric cars rely on dysprosium-enhanced magnets in their electric motors.

    Photo: Wikimedia Commons
  • Metal-halide lamp

    Metal-halide lamp

    Dysprosium iodide is one of the salts that gives these stadium and studio lamps their bright white light.

    Photo: Wikimedia Commons

Research

No research on Dysprosium yet

When Bhavya publishes a project that studies Dysprosium, it will be linked here.

See all research