ChemSphere
68Er167.259

Erbium

Lanthanide · Period 6 · f-block

The pink metal that amplifies the internet's light

Atomic mass
167.259 u
State at 25 °C
Solid
Electronegativity
1.24
Melting point
1,528.9 °C
Boiling point
2,867.9 °C
Configuration
[Xe] 4f12 6s2
Building atom…
68 protons 99 neutrons 68 electrons

Nucleus drawn at reduced count for clarity. Drag to rotate.

Erbium, explained

Video lesson in production

Bhavya’s explainer for this element will play here.

Overview

Erbium is a silvery lanthanide with the configuration [Xe]4f12 6s2, and it forms the Er3+ ion, whose salts and oxide are rose pink. Its value comes from one particular electronic transition: excited Er3+ ions emit light at about 1.55 micrometres. That happens to be the wavelength at which silica optical fibre loses the least light, a coincidence that underpins modern long-distance telecommunications.

In an erbium-doped fibre amplifier, a short length of fibre containing a trace of erbium is pumped by a laser at 980 or 1480 nanometres. Incoming weak signals then stimulate the excited erbium ions to emit identical photons, boosting the signal directly without converting it to electricity. These amplifiers made transoceanic fibre cables practical in the 1990s. Erbium is also used in Er:YAG lasers, whose 2.94-micrometre light is absorbed almost entirely by water, and as a pink colourant in glass and porcelain glazes.

Discovery

Carl Gustaf Mosander discovered erbium in 1843, separating the earth yttria from Ytterby, Sweden, into fractions he named yttria, erbia and terbia. The names erbia and terbia were later swapped, so today's erbium corresponds to Mosander's 'terbia'. Erbium oxide was itself later shown to contain ytterbium, scandium, holmium and thulium. Reasonably pure erbium metal was first produced in 1934 by Wilhelm Klemm and Heinrich Bommer by reducing anhydrous erbium chloride with potassium vapour.

Where it’s found
About 3 parts per million of Earth's crust, obtained from xenotime, euxenite and ion-adsorption clays.
What it’s used for
  • Fibre-optic signal amplifiers
  • Er:YAG medical and dental lasers
  • Pink glass and glazes
  • Nuclear control-rod alloys
  • Vanadium alloys
In living things
No known biological role; erbium compounds have low toxicity.
Safety
Low hazard in bulk; powdered metal is flammable.

How it compares

Where Erbium sits among all 118 elements on the trends that shape the table.

  • Electronegativity1.24Pauling

    #75 of 100 elements with data

  • Ionization energy589kJ/mol

    #73 of 104 elements with data

  • Atomic radius175pm

    #25 of 95 elements with data

  • Electron affinity30.1kJ/mol

    #71 of 109 elements with data

  • Density9.07g/cm³

    #45 of 114 elements with data

  • Melting point1,800K

    #28 of 110 elements with data

Density
9.07 g/cm³
Atomic radius
175 pm
Covalent radius
165 pm
Molar heat
28.12 J/(mol·K)
Appearance
silvery white
Discovered by
Carl Gustaf Mosander

Inside the atom

68 electrons arranged in 6 shells: 2 · 8 · 18 · 30 · 8 · 2.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f12 · shorthand [Xe] 4f12 6s2

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d10
  8. 4p6
  9. 5s2
  10. 4d10
  11. 5p6
  12. 6s2
  13. 4f12

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Erbium bonds.

Ionization energies

Energy to remove each electron in turn, on a log scale. Each electron is harder to remove than the last, because the remaining ones feel more of the nucleus.

Signature reactions

The chemistry Erbium is known for.

  1. Redox · Combustion

    Burning in air

    Erbium burns to form erbium(III) oxide, a pink powder. This oxide is used to colour glass and is the starting point for doping optical fibre.

    4Er(s)+3O2(g)2Er2O3(s)

    Conditions: heating in air

  2. Redox · Single displacement

    Reaction with water

    Erbium reduces water slowly, forming erbium hydroxide and hydrogen. The slower rate compared with lighter lanthanides follows the trend of decreasing reactivity across the series.

    2Er(s)+6H2O(l)2Er(OH)3(s)+3H2(g)

    Conditions: slow in cold water, faster when hot

  3. Redox · Synthesis

    Reaction with chlorine

    Erbium combines directly with chlorine to form pink-violet erbium(III) chloride. Anhydrous ErCl3 made this way was the compound reduced to give the first pure erbium metal.

    2Er(s)+3Cl2(g)2ErCl3(s)

    Conditions: heating in chlorine gas

Where you’ll meet it

  • Submarine communications cable

    Submarine communications cable

    Repeaters along transoceanic cables use erbium-doped fibre to amplify light signals.

    Photo: Wikimedia Commons
  • Optical fiber

    Optical fiber

    Erbium emits at 1.55 micrometres, the wavelength where silica fibre loses the least light.

    Photo: Wikimedia Commons
  • Er:YAG laser

    Er:YAG laser

    Erbium-doped YAG crystals produce mid-infrared laser light used in skin and dental treatments.

    Photo: Wikimedia Commons
  • Ytterby

    Ytterby

    Erbium is one of four elements named after this Swedish village.

    Photo: Wikimedia Commons

Research

No research on Erbium yet

When Bhavya publishes a project that studies Erbium, it will be linked here.

See all research