ChemSphere
54Xe131.294

Xenon

Noble gas · Period 5 · Group 18 · p-block

The 'stranger' gas that lights cinemas and pushes spacecraft

Atomic mass
131.294 u
State at 25 °C
Gas
Electronegativity
2.6
Melting point
-111.7 °C
Boiling point
-108.1 °C
Configuration
[Kr] 4d10 5s2 5p6
Building atom…
54 protons 77 neutrons 54 electrons

Nucleus drawn at reduced count for clarity. Drag to rotate.

Xenon, explained

Video lesson in production

Bhavya’s explainer for this element will play here.

Overview

Xenon is a dense, colourless noble gas in group 18 with the configuration [Kr] 4d10 5s2 5p6. Like all noble gases, its outer shell is full, but xenon's outermost electrons are far from the nucleus and well shielded, so its first ionization energy is relatively low. That makes xenon the noble gas most willing to react. With highly electronegative partners such as fluorine and oxygen, it forms real compounds, including xenon difluoride, xenon tetrafluoride and the explosive xenon trioxide, with xenon in oxidation states up to +8.

Xenon is rare, about 87 parts per billion of air, and is produced by fractional distillation of liquid air. Passing an electric discharge through it gives an intense white light close to daylight, used in camera flashes, cinema projectors and car headlights. Its heavy atoms are easy to ionize and carry a lot of momentum when accelerated, making xenon the standard propellant for ion thrusters. Xenon is also an effective general anaesthetic with few side effects, though cost limits its use. Tonnes of ultrapure liquid xenon fill underground detectors searching for dark matter.

Discovery

In July 1898 William Ramsay and Morris Travers at University College London were repeatedly distilling liquefied air. After finding krypton and neon, they isolated a heavier gas from the residue that glowed blue in a discharge tube. They named it xenon, from the Greek xenos, meaning 'stranger'. For decades noble gases were thought to be inert, until in 1962 Neil Bartlett at the University of British Columbia made a xenon compound with platinum hexafluoride.

Where it’s found
Xenon makes up about 0.0000087% of Earth's atmosphere and is obtained as a by-product of separating air into oxygen and nitrogen.
What it’s used for
  • Arc lamps and cinema projectors
  • Ion thruster propellant
  • HID car headlights
  • General anaesthesia
  • Dark matter detectors
  • Excimer lasers
In living things
Xenon has no biological role. It is not toxic, but at high concentrations it acts as an anaesthetic and, like any inert gas, can cause suffocation.
Safety
Xenon gas is non-toxic but can displace oxygen in enclosed spaces; some of its compounds, such as xenon trioxide, are powerful oxidizers and explosives.

How it compares

Where Xenon sits among all 118 elements on the trends that shape the table.

  • Electronegativity2.6Pauling

    #8 of 100 elements with data

  • Ionization energy1,170kJ/mol

    #10 of 104 elements with data

  • Atomic radius108pm

    #83 of 95 elements with data

  • Electron affinity-77kJ/mol

    #103 of 109 elements with data

  • Density0.006g/cm³

    #105 of 114 elements with data

  • Melting point161K

    #102 of 110 elements with data

Density
5.89 g/L
Atomic radius
108 pm
Covalent radius
131 pm
Molar heat
—
Appearance
colorless gas, exhibiting a blue glow when placed in a high voltage electric field
Discovered by
William Ramsay

Inside the atom

54 electrons arranged in 5 shells: 2 · 8 · 18 · 18 · 8.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 · shorthand [Kr] 4d10 5s2 5p6

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d10
  8. 4p6
  9. 5s2
  10. 4d10
  11. 5p6

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Xenon bonds.

Ionization energies

Energy to remove each electron in turn, on a log scale. Each electron is harder to remove than the last, because the remaining ones feel more of the nucleus.

Signature reactions

The chemistry Xenon is known for.

  1. Redox · Synthesis

    Bartlett's xenon compound

    Xenon gas reacts with deep-red platinum hexafluoride to give an orange-yellow solid. Bartlett formulated it as xenon hexafluoroplatinate; the real product is a more complex mixture, but it proved that noble gases can react.

    Xe(g)+PtF6(g)XePtF6(s)

    Conditions: room temperature

  2. Redox · Synthesis

    Forming xenon tetrafluoride

    Heating xenon with excess fluorine produces colourless crystals of xenon tetrafluoride. The molecule is square planar, with two lone pairs on xenon, a classic VSEPR example.

    Xe(g)+2F2(g)XeF4(s)

    Conditions: nickel vessel, about 400 °C, 6 atm

  3. Redox · Hydrolysis

    Hydrolysis of xenon difluoride

    Xenon difluoride oxidizes water, releasing oxygen and xenon gas and leaving hydrofluoric acid. This reaction shows XeF2's power as a fluorinating and oxidizing agent.

    2XeF2(s)+2H2O(l)2Xe(g)+4HF(aq)+O2(g)

    Conditions: water, slowly at room temperature

Where you’ll meet it

  • Xenon arc lamp

    Xenon arc lamp

    Xenon arc lamps produce the brilliant white light used in cinema and IMAX projectors.

    Photo: Wikimedia Commons
  • Ion thruster

    Ion thruster

    Ion thrusters accelerate xenon ions to tens of kilometres per second to propel spacecraft.

    Photo: Wikimedia Commons
  • Flash (photography)

    Flash (photography)

    Electronic camera flashes discharge through a xenon-filled tube.

    Photo: Wikimedia Commons
  • LZ experiment

    LZ experiment

    The LZ dark matter detector holds about 10 tonnes of liquid xenon deep underground in South Dakota.

    Photo: Wikimedia Commons

Research

No research on Xenon yet

When Bhavya publishes a project that studies Xenon, it will be linked here.

See all research