Xenon
Noble gas · Period 5 · Group 18 · p-block
The 'stranger' gas that lights cinemas and pushes spacecraft
- Atomic mass
- 131.294 u
- State at 25 °C
- Gas
- Electronegativity
- 2.6
- Melting point
- -111.7 °C
- Boiling point
- -108.1 °C
- Configuration
- [Kr] 4d10 5s2 5p6
Nucleus drawn at reduced count for clarity. Drag to rotate.
Xenon, explained
Video lesson in production
Bhavya’s explainer for this element will play here.
Overview
Xenon is a dense, colourless noble gas in group 18 with the configuration [Kr] 4d10 5s2 5p6. Like all noble gases, its outer shell is full, but xenon's outermost electrons are far from the nucleus and well shielded, so its first ionization energy is relatively low. That makes xenon the noble gas most willing to react. With highly electronegative partners such as fluorine and oxygen, it forms real compounds, including xenon difluoride, xenon tetrafluoride and the explosive xenon trioxide, with xenon in oxidation states up to +8.
Xenon is rare, about 87 parts per billion of air, and is produced by fractional distillation of liquid air. Passing an electric discharge through it gives an intense white light close to daylight, used in camera flashes, cinema projectors and car headlights. Its heavy atoms are easy to ionize and carry a lot of momentum when accelerated, making xenon the standard propellant for ion thrusters. Xenon is also an effective general anaesthetic with few side effects, though cost limits its use. Tonnes of ultrapure liquid xenon fill underground detectors searching for dark matter.
Discovery
In July 1898 William Ramsay and Morris Travers at University College London were repeatedly distilling liquefied air. After finding krypton and neon, they isolated a heavier gas from the residue that glowed blue in a discharge tube. They named it xenon, from the Greek xenos, meaning 'stranger'. For decades noble gases were thought to be inert, until in 1962 Neil Bartlett at the University of British Columbia made a xenon compound with platinum hexafluoride.
- Where it’s found
- Xenon makes up about 0.0000087% of Earth's atmosphere and is obtained as a by-product of separating air into oxygen and nitrogen.
- What it’s used for
- Arc lamps and cinema projectors
- Ion thruster propellant
- HID car headlights
- General anaesthesia
- Dark matter detectors
- Excimer lasers
- In living things
- Xenon has no biological role. It is not toxic, but at high concentrations it acts as an anaesthetic and, like any inert gas, can cause suffocation.
- Safety
- Xenon gas is non-toxic but can displace oxygen in enclosed spaces; some of its compounds, such as xenon trioxide, are powerful oxidizers and explosives.
How it compares
Where Xenon sits among all 118 elements on the trends that shape the table.
- Electronegativity2.6Pauling
#8 of 100 elements with data
- Ionization energy1,170kJ/mol
#10 of 104 elements with data
- Atomic radius108pm
#83 of 95 elements with data
- Electron affinity-77kJ/mol
#103 of 109 elements with data
- Density0.006g/cm³
#105 of 114 elements with data
- Melting point161K
#102 of 110 elements with data
- Density
- 5.89 g/L
- Atomic radius
- 108 pm
- Covalent radius
- 131 pm
- Molar heat
- —
- Appearance
- colorless gas, exhibiting a blue glow when placed in a high voltage electric field
- Discovered by
- William Ramsay
Inside the atom
54 electrons arranged in 5 shells: 2 · 8 · 18 · 18 · 8.
Orbital diagram
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 · shorthand [Kr] 4d10 5s2 5p6
- 1s2
- 2s2
- 2p6
- 3s2
- 3p6
- 4s2
- 3d10
- 4p6
- 5s2
- 4d10
- 5p6
Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Xenon bonds.
Ionization energies
Signature reactions
The chemistry Xenon is known for.
Redox · Synthesis
Bartlett's xenon compound
Xenon gas reacts with deep-red platinum hexafluoride to give an orange-yellow solid. Bartlett formulated it as xenon hexafluoroplatinate; the real product is a more complex mixture, but it proved that noble gases can react.
Conditions: room temperature
Redox · Synthesis
Forming xenon tetrafluoride
Heating xenon with excess fluorine produces colourless crystals of xenon tetrafluoride. The molecule is square planar, with two lone pairs on xenon, a classic VSEPR example.
Conditions: nickel vessel, about 400 °C, 6 atm
Redox · Hydrolysis
Hydrolysis of xenon difluoride
Xenon difluoride oxidizes water, releasing oxygen and xenon gas and leaving hydrofluoric acid. This reaction shows XeF2's power as a fluorinating and oxidizing agent.
Conditions: water, slowly at room temperature
Where you’ll meet it

Xenon arc lamp
Xenon arc lamps produce the brilliant white light used in cinema and IMAX projectors.
Photo: Wikimedia Commons
Ion thruster
Ion thrusters accelerate xenon ions to tens of kilometres per second to propel spacecraft.
Photo: Wikimedia Commons
Flash (photography)
Electronic camera flashes discharge through a xenon-filled tube.
Photo: Wikimedia Commons
LZ experiment
The LZ dark matter detector holds about 10 tonnes of liquid xenon deep underground in South Dakota.
Photo: Wikimedia Commons
Research
No research on Xenon yet
When Bhavya publishes a project that studies Xenon, it will be linked here.