Mendelevium
Actinide · Period 7 · f-block
Named for the periodic table's architect, made 17 atoms at a time
- Atomic mass
- 258 u
- State at 25 °C
- Solid
- Electronegativity
- 1.3
- Melting point
- 826.9 °Cpredicted
- Boiling point
- —
- Configuration
- [Rn] 5f13 7s2
Nucleus drawn at reduced count for clarity. Drag to rotate.
Mendelevium, explained
Video lesson in production
Bhavya’s explainer for this element will play here.
Overview
Mendelevium is a radioactive actinide, the ninth element beyond uranium and the first that cannot be made by neutron capture in a reactor. Its atoms carry a 5f13 7s2 electron configuration, so like its lighter actinide neighbors it usually gives up three electrons to form the Md3+ ion. No visible amount has ever been isolated; every property has been measured on samples of a few thousand atoms or fewer, using tracer techniques where mendelevium is followed by its radioactivity.
Its chemistry has one twist. Because adding one more electron completes the 5f subshell at 5f14, mendelevium is unusually easy to reduce to the +2 state in water, more so than most actinides. In ion-exchange columns Md3+ elutes just before fermium, exactly where the actinide contraction predicts, which is how its position in the table was confirmed. The longest-lived isotope, mendelevium-258, has a half-life of about 51 days, long enough for slow, careful chemistry experiments.
Discovery
Albert Ghiorso, Bernard Harvey, Gregory Choppin, Stanley Thompson and Glenn Seaborg made mendelevium at Berkeley in early 1955 by bombarding about a billion atoms of einsteinium-253 with alpha particles in the 60-inch cyclotron. They identified 17 atoms in total, racing each sample to their detectors before its atoms decayed. It was named for Dmitri Mendeleev, the creator of the periodic table, a pointed choice by American scientists during the Cold War.
- Where it’s found
- Mendelevium does not occur in nature; it is made by bombarding einsteinium or lighter actinides with charged particles in accelerators.
- What it’s used for
- Nuclear physics research
- Actinide chemistry studies
- Testing periodic trends
- Fermium isotope production
- In living things
- Mendelevium has no biological role. It is intensely radioactive and would be toxic, but too little exists to pose any real exposure.
- Safety
- Radioactive and produced only in quantities of thousands or millions of atoms; handled solely in specialized nuclear laboratories.
How it compares
Where Mendelevium sits among all 118 elements on the trends that shape the table.
- Electronegativity1.3Pauling
#62 of 100 elements with data · predicted
- Ionization energy635kJ/mol
#59 of 104 elements with data · predicted
- Atomic radiusNo data
Not measured for this element
- Electron affinity93.9kJ/mol
#31 of 109 elements with data · predicted
- DensityNo data
Not measured for this element
- Melting point1,100K
#58 of 110 elements with data · predicted
- Density
- —
- Atomic radius
- —
- Covalent radius
- —
- Molar heat
- —
- Appearance
- —
- Discovered by
- Lawrence Berkeley National Laboratory
Inside the atom
101 electrons arranged in 7 shells: 2 · 8 · 18 · 32 · 31 · 8 · 2.
Orbital diagram
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f13 · shorthand [Rn] 5f13 7s2
- 1s2
- 2s2
- 2p6
- 3s2
- 3p6
- 4s2
- 3d10
- 4p6
- 5s2
- 4d10
- 5p6
- 6s2
- 4f14
- 5d10
- 6p6
- 7s2
- 5f13
Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Mendelevium bonds.
Signature reactions
How the first atoms were made, and how they fall apart.
Nuclear · Alpha capture
Discovery synthesis
An einsteinium-253 nucleus absorbs an alpha particle and ejects one neutron, raising its atomic number from 99 to 101. Only about one atom per hour of bombardment was produced, so the team collected recoiling atoms on a thin gold foil behind the target.
Conditions: alpha-particle beam, Berkeley 60-inch cyclotron, 1955
Nuclear · Electron capture
Electron capture decay
Mendelevium-256 mostly decays by capturing an inner-shell electron, turning a proton into a neutron and emitting a neutrino. The fermium-256 daughter then undergoes spontaneous fission, and those fission events were the signals Ghiorso's team counted to prove mendelevium had formed.
Conditions: spontaneous, half-life about 77 minutes
Redox · Aqueous
Reduction to Md(II)
In 1967 tracer experiments showed that Md3+ can be reduced to Md2+ in aqueous solution, with a standard potential near -0.1 V. This is a measured result and an early sign that the late actinides favor the +2 state as the 5f shell fills.
Conditions: tracer scale, strong reducing agents in acidic solution
Where you’ll meet it

Dmitri Mendeleev
The Russian chemist who arranged the periodic table and predicted undiscovered elements gives element 101 its name.
Photo: Wikimedia Commons
Periodic table
Mendelevium's placement after fermium was confirmed by where it eluted from ion-exchange columns, exactly as the table predicts.
Photo: Wikimedia Commons
Albert Ghiorso
Ghiorso co-discovered mendelevium and built the detectors that caught its handful of atoms.
Photo: Wikimedia Commons
Lawrence Berkeley National Laboratory
Berkeley's cyclotrons produced mendelevium in 1955, one of many elements first made on this hillside.
Photo: Wikimedia Commons
Research
No research on Mendelevium yet
When Bhavya publishes a project that studies Mendelevium, it will be linked here.