ChemSphere
101Md258

Mendelevium

Actinide · Period 7 · f-block

Named for the periodic table's architect, made 17 atoms at a time

Atomic mass
258 u
State at 25 °C
Solid
Electronegativity
1.3
Melting point
826.9 °Cpredicted
Boiling point
—
Configuration
[Rn] 5f13 7s2
Building atom…
101 protons 157 neutrons 101 electrons

Nucleus drawn at reduced count for clarity. Drag to rotate.

Mendelevium, explained

Video lesson in production

Bhavya’s explainer for this element will play here.

Overview

Mendelevium is a radioactive actinide, the ninth element beyond uranium and the first that cannot be made by neutron capture in a reactor. Its atoms carry a 5f13 7s2 electron configuration, so like its lighter actinide neighbors it usually gives up three electrons to form the Md3+ ion. No visible amount has ever been isolated; every property has been measured on samples of a few thousand atoms or fewer, using tracer techniques where mendelevium is followed by its radioactivity.

Its chemistry has one twist. Because adding one more electron completes the 5f subshell at 5f14, mendelevium is unusually easy to reduce to the +2 state in water, more so than most actinides. In ion-exchange columns Md3+ elutes just before fermium, exactly where the actinide contraction predicts, which is how its position in the table was confirmed. The longest-lived isotope, mendelevium-258, has a half-life of about 51 days, long enough for slow, careful chemistry experiments.

Discovery

Albert Ghiorso, Bernard Harvey, Gregory Choppin, Stanley Thompson and Glenn Seaborg made mendelevium at Berkeley in early 1955 by bombarding about a billion atoms of einsteinium-253 with alpha particles in the 60-inch cyclotron. They identified 17 atoms in total, racing each sample to their detectors before its atoms decayed. It was named for Dmitri Mendeleev, the creator of the periodic table, a pointed choice by American scientists during the Cold War.

Where it’s found
Mendelevium does not occur in nature; it is made by bombarding einsteinium or lighter actinides with charged particles in accelerators.
What it’s used for
  • Nuclear physics research
  • Actinide chemistry studies
  • Testing periodic trends
  • Fermium isotope production
In living things
Mendelevium has no biological role. It is intensely radioactive and would be toxic, but too little exists to pose any real exposure.
Safety
Radioactive and produced only in quantities of thousands or millions of atoms; handled solely in specialized nuclear laboratories.

How it compares

Where Mendelevium sits among all 118 elements on the trends that shape the table.

  • Electronegativity1.3Pauling

    #62 of 100 elements with data · predicted

  • Ionization energy635kJ/mol

    #59 of 104 elements with data · predicted

  • Atomic radiusNo data

    Not measured for this element

  • Electron affinity93.9kJ/mol

    #31 of 109 elements with data · predicted

  • DensityNo data

    Not measured for this element

  • Melting point1,100K

    #58 of 110 elements with data · predicted

Density
—
Atomic radius
—
Covalent radius
—
Molar heat
—
Appearance
—
Discovered by
Lawrence Berkeley National Laboratory

Inside the atom

101 electrons arranged in 7 shells: 2 · 8 · 18 · 32 · 31 · 8 · 2.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f13 · shorthand [Rn] 5f13 7s2

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d10
  8. 4p6
  9. 5s2
  10. 4d10
  11. 5p6
  12. 6s2
  13. 4f14
  14. 5d10
  15. 6p6
  16. 7s2
  17. 5f13

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Mendelevium bonds.

Signature reactions

How the first atoms were made, and how they fall apart.

  1. Nuclear · Alpha capture

    Discovery synthesis

    An einsteinium-253 nucleus absorbs an alpha particle and ejects one neutron, raising its atomic number from 99 to 101. Only about one atom per hour of bombardment was produced, so the team collected recoiling atoms on a thin gold foil behind the target.

    253Es+4He256Md+10n

    Conditions: alpha-particle beam, Berkeley 60-inch cyclotron, 1955

  2. Nuclear · Electron capture

    Electron capture decay

    Mendelevium-256 mostly decays by capturing an inner-shell electron, turning a proton into a neutron and emitting a neutrino. The fermium-256 daughter then undergoes spontaneous fission, and those fission events were the signals Ghiorso's team counted to prove mendelevium had formed.

    256Md+e−256Fm

    Conditions: spontaneous, half-life about 77 minutes

  3. Redox · Aqueous

    Reduction to Md(II)

    In 1967 tracer experiments showed that Md3+ can be reduced to Md2+ in aqueous solution, with a standard potential near -0.1 V. This is a measured result and an early sign that the late actinides favor the +2 state as the 5f shell fills.

    Md3+(aq)+e−Md2+(aq)

    Conditions: tracer scale, strong reducing agents in acidic solution

Where you’ll meet it

  • Dmitri Mendeleev

    Dmitri Mendeleev

    The Russian chemist who arranged the periodic table and predicted undiscovered elements gives element 101 its name.

    Photo: Wikimedia Commons
  • Periodic table

    Periodic table

    Mendelevium's placement after fermium was confirmed by where it eluted from ion-exchange columns, exactly as the table predicts.

    Photo: Wikimedia Commons
  • Albert Ghiorso

    Albert Ghiorso

    Ghiorso co-discovered mendelevium and built the detectors that caught its handful of atoms.

    Photo: Wikimedia Commons
  • Lawrence Berkeley National Laboratory

    Lawrence Berkeley National Laboratory

    Berkeley's cyclotrons produced mendelevium in 1955, one of many elements first made on this hillside.

    Photo: Wikimedia Commons

Research

No research on Mendelevium yet

When Bhavya publishes a project that studies Mendelevium, it will be linked here.

See all research