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21Sc44.956

Scandium

Transition metal · Period 4 · Group 3 · d-block

The rare light metal that makes aluminium alloys tougher

Atomic mass
44.956 u
State at 25 °C
Solid
Electronegativity
1.36
Melting point
1,540.9 °C
Boiling point
2,835.9 °C
Configuration
[Ar] 3d1 4s2
Building atom…
21 protons 24 neutrons 21 electrons

Scandium, explained

Overview

Scandium opens the d-block: its atoms carry the configuration [Ar]3d1 4s2, just one electron in the 3d subshell. That lone d electron and the two 4s electrons are lost together, so scandium's chemistry is almost entirely that of the Sc3+ ion. Because Sc3+ has the electron arrangement of argon, with no d electrons left, its compounds are colorless and nonmagnetic, quite unlike the vividly colored salts of its neighbors. In practice scandium behaves more like aluminium, yttrium and the lanthanides than like a typical transition metal, and it is usually counted among the rare earth elements.

The metal is soft, silvery and light (2.99 g/cm3), melting at 1541 °C. Scandium is not especially scarce, at about 22 parts per million of Earth's crust, more than lead, but it almost never concentrates into rich ores, so world output is only a few tens of tonnes of oxide a year. Its most valuable use is in aluminium: adding 0.1 to 0.5 percent scandium creates tiny Al3Sc particles that pin the metal's grain structure, raising strength and making welds far less prone to cracking.

Discovery

Dmitri Mendeleev predicted an element he called eka-boron in 1871. In 1879 the Swedish chemist Lars Fredrik Nilson found a new oxide while analyzing the Scandinavian minerals euxenite and gadolinite, and named the element after Scandinavia (Latin Scandia). His colleague Per Teodor Cleve soon showed that its properties matched Mendeleev's eka-boron. Metallic scandium was first produced in 1937 by electrolysing a molten mixture of potassium, lithium and scandium chlorides.

Where it’s found
Widely dispersed in the crust at about 22 ppm but rarely concentrated, scandium is recovered mainly as a by-product of processing uranium, titanium, rare-earth and nickel–cobalt laterite ores.
What it’s used for
  • Aluminium–scandium alloys
  • Metal-halide stadium lamps
  • Solid oxide fuel cells
  • Sports equipment frames
  • Aerospace components
In living things
Scandium has no known biological role. Its compounds appear to have low toxicity, though they have not been studied in depth.
Safety
Bulk scandium is not considered hazardous, but fine powder can ignite in air. Scandium salts should be handled as mild irritants.

How it compares

Where Scandium sits among all 118 elements on the trends that shape the table.

  • Electronegativity1.36Pauling

    #58 of 100 elements with data

  • Ionization energy633kJ/mol

    #60 of 104 elements with data

  • Atomic radius160pm

    #36 of 95 elements with data

  • Electron affinity18kJ/mol

    #75 of 109 elements with data

  • Density2.98g/cm³

    #87 of 114 elements with data

  • Melting point1,810K

    #26 of 110 elements with data

Density
2.98 g/cm³
Atomic radius
160 pm
Covalent radius
148 pm
Molar heat
25.52 J/(mol·K)
Appearance
silvery white
Discovered by
Lars Fredrik Nilson

Inside the atom

21 electrons arranged in 4 shells: 2 · 8 · 9 · 2.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d1 · shorthand [Ar] 3d1 4s2

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d1

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Scandium bonds.

Ionization energies

Energy to remove each electron in turn, on a log scale. The biggest leap, from electron 19 to 20 (×4.4), is where the next electron has to come from a filled shell much closer to the nucleus.

Signature reactions

The chemistry Scandium is known for.

  1. Redox · Combustion

    Burning in oxygen

    Scandium burns brightly to form scandium(III) oxide, a white, high-melting solid called scandia. The product shows scandium's strong preference for the +3 oxidation state. Scandia is the starting material for most scandium chemistry and alloys.

    4Sc(s)+3O2(g)2Sc2O3(s)

    Conditions: heating in air

  2. Redox · Single displacement

    Dissolving in hydrochloric acid

    Scandium is an electropositive metal and dissolves readily in acids, releasing hydrogen bubbles. The colorless solution contains Sc3+ ions, which have no d electrons to absorb visible light.

    2Sc(s)+6HCl(aq)2ScCl3(aq)+3H2(g)

    Conditions: dilute acid, room temperature

  3. Redox · Metal extraction

    Calciothermic reduction to the metal

    Scandium fluoride is reduced by calcium metal, the standard industrial route to pure scandium. Calcium is used because it is a stronger reducing agent than scandium and its fluoride separates cleanly as a slag.

    2ScF3(s)+3Ca(s)2Sc(s)+3CaF2(s)

    Conditions: about 1600 °C, inert atmosphere, tantalum crucible

Where you’ll meet it

  • Thortveitite

    Thortveitite

    Thortveitite, Sc2Si2O7, is the richest natural source of scandium, found mainly in Norwegian and Madagascan pegmatites.

    Photo: Wikimedia Commons
  • Metal-halide lamp

    Metal-halide lamp

    Scandium iodide in metal-halide lamps helps produce the bright, sunlight-like light used in stadiums and film studios.

    Photo: Wikimedia Commons
  • MiG-29

    MiG-29

    Soviet engineers used aluminium–scandium alloys in components of the MiG-29 to save weight.

    Photo: Wikimedia Commons
  • Baseball bat

    Baseball bat

    Some high-performance aluminium baseball bats use scandium alloys for extra strength at low weight.

    Photo: Wikimedia Commons

Research

No research on Scandium yet

When Bhavya publishes a project that studies Scandium, it will be linked here.

See all research