ChemSphere
52Te127.603

Tellurium

Metalloid · Period 5 · Group 16 · p-block

A rare metalloid that turns sunlight into power and breath into garlic

Atomic mass
127.603 u
State at 25 °C
Solid
Electronegativity
2.1
Melting point
449.5 °C
Boiling point
987.9 °C
Configuration
[Kr] 4d10 5s2 5p4
Building atom…
52 protons 76 neutrons 52 electrons

Nucleus drawn at reduced count for clarity. Drag to rotate.

Tellurium, explained

Video lesson in production

Bhavya’s explainer for this element will play here.

Overview

Tellurium is a brittle, silver-white metalloid in group 16, below selenium and above polonium. With the configuration [Kr] 4d10 5s2 5p4, it can gain two electrons to form telluride ions (−2), as in cadmium telluride, or use its valence electrons in the +4 and +6 states, as in tellurium dioxide and telluric acid. Crystalline tellurium consists of spiral chains of atoms, like selenium, and it is a semiconductor whose conductivity rises slightly when light falls on it. Down group 16, metallic character increases, and tellurium sits close to the line between metals and non-metals.

Tellurium is one of the rarest stable elements in Earth's crust, roughly as scarce as platinum. During the planet's formation it probably combined with hydrogen to form volatile hydrogen telluride, which escaped into space. Most tellurium is recovered from the anode slimes of copper refineries. Its largest use is in cadmium telluride solar panels, whose thin films absorb sunlight more strongly than silicon. Bismuth telluride is the standard material for thermoelectric coolers, which pump heat when a current flows, and germanium-antimony-tellurium alloys store data in rewritable optical discs by switching between crystalline and glassy states.

Discovery

In 1782 Franz-Joseph Müller von Reichenstein, an Austrian mining inspector in Transylvania, examined a gold ore from Zlatna that yielded a metal-like substance he could not identify. He sent a sample to Martin Heinrich Klaproth in Berlin, who confirmed in 1798 that it was a new element. Klaproth named it tellurium, from the Latin tellus, meaning 'earth', fittingly for an element later paired with selenium, named after the Moon.

Where it’s found
Tellurium occurs at only about 1 part per billion in the crust and is obtained almost entirely as a by-product of copper refining.
What it’s used for
  • Cadmium telluride solar panels
  • Thermoelectric coolers
  • Rewritable optical discs
  • Free-machining steel and copper
  • Rubber vulcanization
In living things
Tellurium has no known role in humans and is mildly toxic. Some fungi and bacteria can incorporate it into amino acids in place of sulfur or selenium.
Safety
Tellurium compounds are toxic, and hydrogen telluride is a poisonous gas; even small exposures cause garlic-smelling breath, headaches and drowsiness.

How it compares

Where Tellurium sits among all 118 elements on the trends that shape the table.

  • Electronegativity2.1Pauling

    #26 of 100 elements with data

  • Ionization energy869kJ/mol

    #26 of 104 elements with data

  • Atomic radius140pm

    #52 of 95 elements with data

  • Electron affinity190kJ/mol

    #10 of 109 elements with data

  • Density6.24g/cm³

    #72 of 114 elements with data

  • Melting point723K

    #72 of 110 elements with data

Density
6.24 g/cm³
Atomic radius
140 pm
Covalent radius
136 pm
Molar heat
25.73 J/(mol·K)
Appearance
—
Discovered by
Franz-Joseph Müller von Reichenstein

Inside the atom

52 electrons arranged in 5 shells: 2 · 8 · 18 · 18 · 6.

Orbital diagram

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p4 · shorthand [Kr] 4d10 5s2 5p4

  1. 1s2
  2. 2s2
  3. 2p6
  4. 3s2
  5. 3p6
  6. 4s2
  7. 3d10
  8. 4p6
  9. 5s2
  10. 4d10
  11. 5p4

Each box is an orbital holding up to two electrons of opposite spin. Highlighted subshells hold the valence electrons that decide how Tellurium bonds.

Ionization energies

Energy to remove each electron in turn, on a log scale. Each electron is harder to remove than the last, because the remaining ones feel more of the nucleus.

Signature reactions

The chemistry Tellurium is known for.

  1. Redox · Combustion

    Burning in air

    Tellurium burns with a blue-green flame to form white tellurium dioxide. TeO2 is used to make dense tellurite glasses for optical fibres.

    Te(s)+O2(g)TeO2(s)

    Conditions: heated in air

  2. Synthesis · Combination

    Forming cadmium telluride

    Cadmium and tellurium combine directly to form black cadmium telluride, a semiconductor with a band gap of about 1.5 eV, close to ideal for absorbing sunlight. Solar panels use a layer only a few micrometres thick.

    Cd(s)+Te(s)CdTe(s)

    Conditions: heated together in a sealed tube

  3. Acid–base

    Dissolving in alkali

    Tellurium dioxide is amphoteric and dissolves in alkali as sodium tellurite. Refiners use this step to separate tellurium from copper refinery slimes before reducing it back to the element.

    TeO2(s)+2NaOH(aq)Na2TeO3(aq)+H2O(l)

    Conditions: aqueous sodium hydroxide

Where you’ll meet it

  • Calaverite

    Calaverite

    Calaverite is a gold telluride, one of the rare minerals in which gold is chemically combined.

    Photo: Wikimedia Commons
  • Thermoelectric cooling

    Thermoelectric cooling

    Thermoelectric coolers pump heat using semiconductor blocks of bismuth telluride.

    Photo: Wikimedia Commons
  • Cadmium telluride photovoltaics

    Cadmium telluride photovoltaics

    Thin-film cadmium telluride panels are the second most common solar technology after silicon.

    Photo: Wikimedia Commons
  • Kalgoorlie

    Kalgoorlie

    Kalgoorlie's gold rush was built partly on gold telluride ores.

    Photo: Wikimedia Commons

Research

No research on Tellurium yet

When Bhavya publishes a project that studies Tellurium, it will be linked here.

See all research