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What happens in a gas stove flame

Combustion of methane · Combustion · Redox · Exothermic

Every blue flame on a gas stove is turning one invisible gas into two others.

Reactants approach

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Energy profileEa illustrative
EnergyProgressEaΔHreactantsproducts

ΔH = -802 kJ · exothermic, releases heat

CH4(g)+2O2(g)CO2(g)+2H2O(g)

ΔH per mol CH4, water formed as vapour.

Meet the molecules

  • Reactantgas

    CH4

    methane

  • Reactantgas

    O2

    oxygen

  • Productgas

    CO2

    carbon dioxide

  • Productgas

    H2O

    water vapour

What you notice

Natural gas piped to a kitchen stove is mostly methane, CH4. When you turn the knob, gas mixes with air at the burner holes and a spark lights it. A well-adjusted flame burns blue because the methane gets enough oxygen to burn completely; a yellow, sooty flame means too little air, so some carbon is left unburned as glowing particles. Hold a cold metal spoon above the flame for a second and it fogs with water, one of the two products. The other, carbon dioxide, is invisible.

Try it

With an adult present, hold a cold steel spoon by its handle above a blue gas flame for one or two seconds and watch water condense on it; let it cool before touching the bowl.

Safety: Incomplete combustion makes carbon monoxide, an odourless poison, so gas appliances need ventilation and a carbon monoxide alarm nearby.

Step by step

  1. 1

    Bonds break first

    Methane's four C–H bonds and oxygen's O=O double bonds must be pulled apart. The spark supplies the first push; after that, the flame's own heat keeps the reaction going.

  2. 2

    Carbon finds oxygen

    The carbon atom bonds to two oxygen atoms, forming a linear CO2 molecule held together by two strong C=O double bonds.

  3. 3

    Hydrogen finds oxygen

    The four hydrogen atoms pair up with the remaining two oxygen atoms to make two bent H2O molecules.

  4. 4

    Net energy out

    The new C=O and O–H bonds are stronger than the C–H and O=O bonds that broke, so about 802 kJ is released for every mole (16 g) of methane burned.

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